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- Most Rev. Adolph Marx
- His Eminence Humberto Cardinal Medeiros
- Most Rev. John J. Fitzpatrick
- Most Rev. Enrique San Pedro
- Most Rev. Raymundo J. Peña
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Most Rev. Adolph MarxFirst Bishop of Brownsville
Appointed: July 21, 1965
Installed: September 2, 1965
Died: November 1, 1965 (Bishop of Brownsville)
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His Eminence Humberto Cardinal MedeirosSecond Bishop of Brownsville
Appointed: April 14, 1966
Installed: June 29, 1966
Appointed Archbishop of Boston: Sept. 8, 1970
Elevated to Cardinal: March 5, 1973
Died: September 17, 1983
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Most Rev. John J. FitzpatrickThird Bishop of Brownsville
Appointed: April 27, 1971
Installed: May 27, 1971
Retired: November 30, 1991
Died: July 15, 2006 (Bishop Emeritus of Brownsville)
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Most Rev. Enrique San PedroFourth Bishop of Brownsville
Appointed: August 13, 1991 (Coadjutor Bishop)
Installed: September 26, 1991(Coadjutor Bishop)
Succeeded to the See: Nov. 30, 1991 (Bishop)
Died: July 17, 1994 (Bishop of Brownsville)
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Most Rev. Raymundo J. PeñaFifth Bishop of Brownsville
Appointed: May 23, 1995
Installed: August 6, 1995
Retired: December 9, 2009
Died: September 24, 2021 (Bishop Emeritus of Brownsville)Curriculum Vitae